Tuesday, September 23, 2008

Stoichiometry

Stoichiometry rests upon the law of conservation of mass, the law of definite proportions (i.e., the law of constant composition) and the law of multiple proportions. In general, chemical reactions combine in definite ratios of chemicals. Since chemical reactions can neither create nor destroy matter, nor transmute one element into another, hence can not make change in form, nature, or substance, the amount of each element must be the same throughout the overall reaction. For example, the amount of element X on the reactant side must equal the amount of element X on the product side.

Wikipedia




"Experimental Essays"

There can scarcely be a doubt entertained respecting the reducibility of all elastic fluids of whatever kind, into liquids; and we ought not to despair of affecting it in low temperatures and by strong pressures exerted upon the unmixed gases further.

Second Essay

I see no sufficient reason why we may not conclude that all elastic fluids under the same pressure expand equally by heat and that for any given expansion of mercury, the corresponding expansion of air is proportionally something less, the higher the temperature. It seems, therefore, that general laws respecting the absolute quantity and the nature of heat are more likely to be derived from elastic fluids than from other substances.

Fourth Essay

John Dalton, Memoirs of the Lit & Phil, 1802